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Controlling the polymer architecture enabled the synthesis of polymer micelles with tethered PAA loops, which will be opened to build uniform corona when desired. Threemiktoarm star and dendrimers with miktoarms containing PSTY, polytertbutyl acrylate (PtBA), polymethyl acrylate (PMA) and PAA were then synthesized working with a combination of Atom Transfer Radical Polymerization (ATRP) and Huisgen 1,3dipolar cycloaddition 'click' reactions. In all reactions, celebs and dendrimers were welldefined with PDIs cheaper than 1.09.
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